Organometallic Chemistry - Lecture 10 - Reductive Elimination | Forming C-C Bonds
Автор: Arca Anil
Загружено: 2025-11-13
Просмотров: 8
In this video, I talked about reductive elimination reactions. This reaction is crucial for forming C-C, C-H, and C-X bonds. Reductive elimination is the reverse form of the oxidative addition. The oxidation state of the metal center decreases. The electron count of the complex also decreases by 2. It is observed for metal centers with high oxidation states. I showed a few examples to explain the concept.
Resource:
Spessard, G. O.; Miessler, G. L. Organometallic Chemistry, 2nd ed.; Oxford University Press: New York, 2010; Chapter 7.
Timecodes:
0:00 – Reductive Elimination Reaction
5:08 – Formation of C–C Bonds
6:32 – Cis Elimination Reaction
9:02 – 1,2-Elimination Reaction
11:12 – Reductive Elimination and Its Effect on the Rh Complex
12:38 – Example: CH₄ Formation Mechanism
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