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Stereochemistry of the Diels-Alder reaction
Автор: ChemWis
Загружено: 2019-11-16
Просмотров: 16179
Описание:
In a Diels-alder reaction there are two components, diene and dienophile. During Diels-alder reaction stereochemistry of the dienophile remains unchanged. There is the possibility for the formation of two diastereomers, endo and exo. Exo is thermodynamically more stable than endo. Endo product is the kinetic while exo is thermodynamic product. Endo is the major product because it is formed at a faster rate than exo due to stabilization of endo transition state due to secondary orbital overlap.
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