Thermodynamic Potentials &Maxwell Relations| Unit 2 Thermal Physics.part-7.

UNIT-II.Thermodynamic Potentials: Extensive and Intensive Thermodynamic Variables. Internal Energy, Enthalpy, Helmholtz Free Energy, Gibbs Free Energy, Their Definitions, Properties and Applications, Surface Films and Variation of Surface Tension with Temperature, Magnetic Work, Cooling due to adiabatic demagnetization. Phase Transitions: First and second order Phase Transitions with examples, Clausius Clapeyron Equation and Ehrenfest equations. Maxwells Thermodynamic Relations: Derivations and applications of Maxwells Relations, Maxwells Relations: (1) Clausius Clapeyron equation (2) Relation between Cp and Cv (3) TdS Equations, (4) Joule- Kelvin coefficient for Ideal and. Vander Waal Gases (5) Energy equations (6) Change of Temperature during Adiabatic Process.


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