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radical additions of HX to alkenes
Автор: Erland Stevens
Загружено: 2019-01-22
Просмотров: 556
Описание:
HX can be added to alkenes through a radical process to give anti-Markovnikov regioselectivity. The only difference is the addition of H2O2 to the reaction. In the initiation step, H2O2 homolytically cleaves to form 2 hydroxyl radicals. These radicals react with HCl to form Cl radicals. In the propagation steps, the Cl radical attacks the alkene on the less highly substituted end to form a more highly substituted radical. The new carbon radical then removes a hydrogen atom from HCl to generate the final product and another Cl radical.
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